Journal of Applied Science and Engineering

Published by Tamkang University Press

1.30

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1.60

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Chien-Hsueh Shih1, Carl C. Gryte1 and Liao-Ping Cheng This email address is being protected from spambots. You need JavaScript enabled to view it.2,3

1Department of Chemical Engineering and Applied Chemistry, Columbia University, New York, NY 10027, U.S.A.
2Department of Chemical and Materials Engineering, Tamkang University, Tamsui, Taiwan, 251, R.O.C.
3Energy and Opto-Electronic Materials Research Center, Tamkang University, Tamsui, Taiwan, 251, R.O.C.


 

Received: October 24, 2011
Accepted: March 7, 2012
Publication Date: December 1, 2012

Download Citation: ||https://doi.org/10.6180/jase.2012.15.4.06  


ABSTRACT


The ternary mass transfer equations that describe the isothermal immersion process for polyamide membrane preparation were solved. To account for the moving boundary conditions, coordinate transformations were performed both for the membrane and the bath regions. Mutual diffusion coefficients between solvent and polymer were measured and used to derive ternary phenomenological coefficients for mass transfer equations. The calculated precipitation times, concentration profiles, and diffusion trajectories were found to agree with the measured light transmittance data and the membrane morphologies presented previously.


Keywords: Nylon-6, Membrane, Ternary, Diffusion, Precipitation


REFERENCES


  1. [1] Lin, D. J., Chang, C. L., Chen, T. C. and Cheng, L. P., “On the Structure of Porous Poly(Vinylidene Fluoride) Membrane Prepared by Phase Inversion from WaterNMP-PVDF System,” Tamkang Journal of Science and Engineering, Vol. 5, pp. 9598 (2002).
  2. [2] Young, T. H., Chang, H. H., Lin, D. J. and Cheng, L. P., “Surface Modification of Microporous PVDF Membranes for Neuron Culture,” Journal of Membrane Science, Vol. 350, pp. 3241 (2010).
  3. [3] Shih, C. H., Gryte, C. C. and Cheng, L. P., “Morphology of Membranes Formed by Isothermal Precipitation of Polyamide Solutions from Water/Formic Acid Systems,” Journal of Applied Polymer Science, Vol. 96, pp. 944960 (2005).
  4. [4] Young, T. H., Lu, J. N., Lin, D. J., Chang, C. L., Chang, H. H. and Cheng, L. P., “Immobilization of l-Lysine on Dense and Porous Poly(Vinylidene Fluoride) Surfaces for Neuron Culture,” Desalination, Vol. 234, pp. 131 143 (2008).
  5. [5] Lin, K. Y., Wang, D. M. and Lai, J. Y., “NonsolventInduced Gelation and Its Effect on Membrane Morphology,” Macromolecules, Vol. 35, pp. 66976706 (2002).
  6. [6] Zhao, Y. H., Zhu, B. K., Ma, X. T. and Xu, Y. Y., “Porous Membranes Modified by Hyperbranched Polymers: I. Preparation and Characterization of PVDF Membrane Using Hyperbranched Polyglycerol as Additive,” Journal of Membrane Science, Vol. 290, pp. 222229 (2007).
  7. [7] Wang. X., Zhang, L., Sun, D., An, Q. and Chen, H., “Effect of Coagulation Bath Temperature on Formation Mechanism of Poly(Vinylidene Fluoride) Membrane,” Journal of Applied Polymer Science, Vol. 110, pp. 16561663 (2008).
  8. [8] Yeow, L. M., Liu, Y. T. and Li, K. “Morphological Study of Poly(Vinylidene Fluoride) Asymmetric Membranes: Effects of the Solvent, Additive, and Dope Temperature,” Journal of Applied Polymer Science, Vol. 92, pp. 17821789 (2004).
  9. [9] Blanco, J. F., Sublet, J., Nguyen, Q. T. and Schaetzel, P., “Formation and Morphology Studies of Different Polysulfones-Based Membranes Made by Wet Phase Inversion Process,” Journal of Membrane Science, Vol. 283, pp. 2737 (2006).
  10. [10] Khayet, M., Mengual, J. I. and Mastsuura, T., “Porous Hydrophobic/Hydrophilic Composite Membranes: Application in Desalination Using Direct Contact Membrane Distillation,” Journal of Membrane Science, Vol. 252, pp. 101113 (2005).
  11. [11] Cheng, L. P., Dwan, A. H. and Gryte, C. C., “Membrane Formation by Isothermal Precipitation in Polyamide-Formic Acid-Water Systems I. Description of Membrane Morphology,” Journal of Polymer Science, Polymer Physics, Vol. 33, pp. 211222 (1995).
  12. [12] Cheng, L. P., Dwan, A. H. and Gryte, C. C., “Membrane Formation by Isothermal Precipitation in Polyamide-Formic Acid-Water Systems II. Precipitation Dynamics,” Journal of Polymer Science, Polymer Physics, Vol. 33, pp. 223235 (1995).
  13. [13] Cohen, C., Tanny, G. B. and Prager, S., “DiffusionControlled Formation of Porous Structures in Ternary Polymer Systems,” Journal of Polymer Science, Polymer Physics, Vol. 17, pp. 477489 (1979).
  14. [14] Reuvers, A. J., van den Berg, J. W. A. and Smolders, C. A., “Formation of Membranes by Means of Immersion Precipitation: Part I. A Model to Describe Mass Transfer during Immersion Precipitation,” Journal of Membrane Science, Vol. 34, pp. 4565 (1987).
  15. [15] Reuvers, A. J. and Smolders, C. A., “Formation of Membranes by Means of Immersion Precipitation: Part II. the Mechanism of Formation of Membranes Prepared from the System Cellulose Acetate-AcetoneWater,” Journal of Membrane Science, Vol. 34, pp. 6786 (1987).
  16. [16] Tsay, C. S. and McHugh, A. J., “Mass Transfer Modeling of Asymmetric Membrane Formation by Phase Inversion,” Journal of Polymer Science, Polymer Physics, Vol. 28, pp. 13271365 (1990).
  17. [17] Cheng, L. P., Soh, Y. S., Dwan, A. H. and Gryte, C. C., “An Improved Model for Mass Transfer during the Formation of Polymeric Membranes by the Immersion-Precipitation Process,” Journal of Polymer Science, Polymer Physics, Vol. 32, pp. 14131425 (1994).
  18. [18] Cheng, L. P., Dwan, A. H. and Gryte, C. C., “Measurements of Mutual Diffusivities in Concentrated Solutions of Membrane-Forming Polyamides and Cellulose Acetate,” Journal of Applied Polymer Science, Vol. 57, pp. 563572 (1995).
  19. [19] Marinaccio, P. J. and Knight, R. A., U.S. Patent 3,876,738 (1975).
  20. [20] Pall, D. B., U. S. Patent 4,340,479 (1982).
  21. [21] Cheng, L. P., Dwan, A. H. and Gryte, C. C., “Isothermal Phase Behavior of Nylon-6, -66, and -610 Polyamides in Formic Acid-Water Systems,” Journal of Polymer Science, Polymer Physics, Vol. 32, pp. 1183 1190 (1994).
  22. [22] Duda, J. L., Vrentas, J. S., Ju, S. T. and Liu, H. T., “Prediction of Diffusion Coefficients for Polymer-Solvent Systems,” AIChE Journal, Vol. 28, pp. 279285 (1982).
  23. [23] Haase, R., Thermodynamics of Irreversible Process, Addison-Wesley, MA (1969).
  24. [24] Fitts, D. D., Nonequilibrium Thermodynamics, McGraw-Hill, New York (1962).
  25. [25] Cheng, L. P., Mechanism of Microporous Membrane Formation by Precipitation of Semicrystalline Polymers, Ph. D. Dissertation, Columbia University, New York, U.S.A. (1993).
  26. [26] Dunlop, P. J., “Frictional Coefficients for Binary and Ternary Isothermal Diffusion,” Journal of Physical Chemistry, Vol. 68, pp. 2630 (1964).