Journal of Applied Science and Engineering

Published by Tamkang University Press

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Chen-Yu Yeh1 and Shu-Hua Cheng  2

1Department of Chemistry National Chung Hsing University Taichung, Taiwan 402, R.O.C.
2Department of Applied Chemistry National Chi Nan University Puli, Taiwan 545, R.O.C.


 

Received: February 18, 2003
Accepted: March 17, 2003
Publication Date: June 1, 2003

Download Citation: ||https://doi.org/10.6180/jase.2003.6.2.03  


ABSTRACT


Two types of porphyrin free base, meso-tetra(4-vinylphenyl)- porphyrin and meso-tetra(4-stilbenyl)porphyrin, were synthesized and characterized. Metallation was achieved by insertion of MnCl2 . 4H2O. Oxidative electropolymerization of the manganese porphyrin monomers by cyclic scans would anchor the resulting materials on glassy carbon electrodes. It was found that both poly (manganese tetra(4-vinylphenyl)porphyrin) and poly(manganese tetra(4-stilbenyl) porphyrin), (poly-MnTVPP and poly-MnTSP), can serve as electrocatalysts toward dioxygen reduction.


Keywords: Manganese Porphyrin, Electropolymerization, Modified Electrode, Dioxygen Reduction


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