Journal of Applied Science and Engineering

Published by Tamkang University Press

1.30

Impact Factor

1.60

CiteScore

Ruizhi Hu1, Shanfa Tang This email address is being protected from spambots. You need JavaScript enabled to view it.1,2, Musa Mpelwa1, Lijun Jin1, Hong Deng1, Shuyun Feng1, and Zhaowen Jiang1

1School of Petroleum Engineering, Yangtze University, Wuhan, Hubei, China
2Hubei Cooperative Innovation Center of Unconventional Oil and Gas, Yangtze University, Wuhan, Hubei, China 


 

Received: May 6, 2020
Accepted: July 27, 2020
Publication Date: December 1, 2020

 Copyright The Author(s). This is an open access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are cited.


Download Citation: ||https://doi.org/10.6180/jase.202012_23(4).0015  


ABSTRACT


The development of low permeability reservoirs has become the main battlefield for oil field exploitation. However, due to its special and complicated geological conditions, the existing chemical enhanced oil recovery methods cannot meet the needs of the efficient development of low permeability reservoirs. Herein, the low interfacial tension viscoelastic surfactant (GACS) was studied as the potential candidate for low permeability reservoir oil displacing agent. The parameters characterizing the efficiency of chemical flooding for enhanced oil recovery were studied: surface activity, viscosity, oil-water interfacial tension (IFT), and viscoelasticity. The results show that, as a new class of chemicals for EOR under harsh conditions of high salinity, the GACS is made up of a single component, are shear-thinning with good injectivity. The critical micelle concentration (CMC) and surface tension of GACS surfactants are extremely low, which is conducive to the formation of micelles at low concentrations. Under different salinity conditions, the IFT is at the low to ultra-low interfacial tension level, and the surfactant solution demonstrated remarkable viscosifying ability and viscoelasticity. GACS was found to be a potential additive for the enhanced oil recovery application.


Keywords: EOR applications; CMC; low interfacial tension; viscous property; viscoelastic property; Gemini surfactant.


REFERENCES


  1. [1]ALFARGE DHEIAA, WEI, MINGZHEN, and BAI, BAOJUN. (2017) IOR methods in unconventional reservoirs of North America: comprehensive review. SPE Western Regional Meeting, Bakersfield, California, USA.
  2. [2]BALASUBRAMANIAN S, CHEN, P, BOSE, S, ALZAHABI, A, and THAKUR, GC. (2018) Recent Advances in Enhanced Oil Recovery Technologies for Unconventional Oil Reservoirs. Offshore Technology Conference, Houston, Texas, USA.
  3. [3]HU WENRUI, WEI, YI, and BAO, JINGWEI. (2018) Development of the theory and technology for low permeability reservoirs in China. Petrol Explor Dev 4(45), 685-697.
  4. [4]SHENG JAMES J. (2016) Formation damage in chemical enhanced oil recovery processes. Asia‐Pacific Journal of Chemical Engineering 11(6), 826-835.
  5. [5]SIGGEL LORENZ, SANTA, MONIKA, HANSCH, MARKUS, NOWAK, MAIK, RANFT, MEIK, WEISS, HORST, HAJNAL, DAVID, SCHREINER, EDUARD, OETTER, GUENTER, and TINSLEY, JACK. (2012) A new class of viscoelastic surfactants for enhanced oil recovery. SPE Improved Oil Recovery Symposium, Tulsa, Oklahoma, USA.
  6. [6]GHOSH PINAKI, and MOHANTY, KISHORE K. (2018) Novel application of cationic surfactants for foams with wettability alteration in oil-wet low-permeability carbonate rocks. SPE Journal 23(06), 2,218-2,231.
  7. [7]YIN SHIZE, PU, HUI, and ZHOU, SHIDE. (2018) An Update on Full Field Implementation of Chemical Flooding in Daqing Oilfield, China, and Its Future. SPE Improved Oil Recovery Conference, Tulsa, Oklahoma, USA.
  8. [8]ZHU YOUYI, FAN, JIAN, LIU, XIAOXIA, and LI, JIANGUO. (2016) Studies on viscoelastic surfactants for its potential EOR application in the low permeability reservoirs. SPE improved oil recovery conference, Tulsa, Oklahoma, USA.
  9. [9]SIGGEL L, RADLOFF, M, REIMANN, S, HANSCH, M, NOWAK, M, RANFT, M, WEISS, H, SCHREINER, E, and BRAND, F. (2014) TPM's: A New Class of Viscoelastic Solutions for Enhanced Oil Recovery. SPE EOR Conference at Oil and Gas West Asia, Muscat, Oman.
  10. [10]SAMUEL MATHEW, POLSON, DAN, GRAHAM, DON, KORDZIEL, WALT, WAITE, TIM, WATERS, GEORGE, VINOD, PS, FU, DAN, and DOWNEY, RICH. (2000) Viscoelastic surfactant fracturing fluids: applications in low permeability reservoirs. SPE Rocky Mountain regional/low-permeability reservoirs symposium and exhibition, Denver, Colorado.
  11. [11]CHANG FF, ACOCK, AM, GEOGHAGAN, A, and HUCKABEE, PT. (2001) Experience in acid diversion in high permeability deep water formations using visco-elastic-surfactant. SPE Annual Technical Conference and Exhibition, New Orleans, Louisiana, USA.
  12. [12]CHANG FRANK, QU, QI, and FRENIER, WAYNE. (2001) A novel self-diverting-acid developed for matrix stimulation of carbonate reservoirs. SPE International Symposium on Oilfield Chemistry, Houston, Texas, USA.
  13. [13]HULL KATHERINE L, SAYED, MOHAMMED, and AL-MUNTASHERI, GHAITHAN A. (2016) Recent advances in viscoelastic surfactants for improved production from hydrocarbon reservoirs. SPE Journal 21(04), 1,340-1,357.
  14. [14]MYSKA JIRI, and MIK, VACLAV. (2004) Degradation of surfactant solutions by age and by a flow singularity. Chemical Engineering and Processing: Process Intensification 43(12), 1495-1501.
  15. [15]GANZUO LI, JIANHAI, MU, FENG, CHEN, and JUN, XU. (2002) Applications of natural mixed carboxylate on enhanced oil recovery and viscosity-reducing for viscous crude oil. Petroleum Processing and Petrochemicals 33(9), 25-28.
  16. [16]MA D. X., XU, F. H., WANG, Z. L., SUI, C. Y., LI, L. X., and WANG, W. B., (2009) Rheological property and viscosity variation mechanism of variable viscosity diverting acid based on betaine. Special Oil & Gas Resrvoirs 16(3), 89-91.
  17. [17]TANG S., ZHAO, C., TIAN, L., and ZHOU, T., (2016) Temperature-resistance clean fracturing fluid with carboxylate gemini surfactant: A case study of tight sandstone gas reservoirs in the Tarim Basin. Natural Gas Industry 36(6), 45-51.
  18. [18]ZHENG Y. C., ZHAO, L. Q., and LIU, P. L., (2005) Studies on sinapic amido propyl betaine based acidizing fluids of variable viscosity. Oilfield Chemistry 22, 302-306.
  19. [19]BEAUMONT JULIEN, LOUVET, NICOLAS, DIVOUX, THIBAUT, FARDIN, MARC-ANTOINE, BODIGUEL, HUGUES, LEROUGE, SANDRA, MANNEVILLE, SéBASTIEN, and COLIN, ANNIE. (2013) Turbulent flows in highly elastic wormlike micelles. Soft Matter 9(3), 735-749.
  20. [20]KUMAR S, AWANG, MARIYAMNI, AHMED, SHUAIB, DEHRAJ, NAEEM UL, and SALEEM, YASIR SHEIKH. (2015) Worm-Like Micelles as a Mobility Control Agent for Chemical Enhanced Oil Recovery. SPE/IATMI Asia Pacific Oil & Gas Conference and Exhibition, Nusa Dua, Bali, Indonesia.
  21. [21]PAL SREELA, MUSHTAQ, M, BANAT, FAWZI, and AL SUMAITI, ALI M. (2018) Review of surfactant-assisted chemical enhanced oil recovery for carbonate reservoirs: challenges and future perspectives. Petroleum Science 15(1), 77-102.
  22. [22]VAN SANTVOORT JORIS, and GOLOMBOK, MICHAEL. (2015) Viscoelastic surfactants for diversion control in oil recovery. Journal of petroleum science and engineering 135, 671-677.
  23. [23]LU Y. J., FANG, B., FANG, D. Y., YAN, Y. Z., and SHU, Y. H., (2003) Viscoelastic Surfactant Micelle Systems and Their Rheological Properties. Oilfield Chemistry 20, 291-294.
  24. [24]VAN SANTVOORT JORIS, and GOLOMBOK, MICHAEL. (2016) Improved oil reservoir sweep with viscoelastic surfactants. Energy & fuels 30(11), 9226-9232.
  25. [25]YANG JIANG. (2002) Viscoelastic wormlike micelles and their applications. Current Opinion in Colloid & Interface Science 7(5-6), 276-281.
  26. [26]LAKATOS ISTVAN JANOS, TOTH, JANOS, BODI, TIBOR, LAKATOS-SZABO, JULIANNA, BERGER, PAUL DANIEL, and LEE, CHRISTIE H. (2007) Application of viscoelastic surfactants as mobility-control agents in low-tension surfactant floods. International symposium on oilfield chemistry, Houston, Texas, USA.
  27. [27]FAN HAIMING, ZHENG, TONG, CHEN, HAOLIN, HUANG, JUN, WEI, ZHIYI, KANG, WANLI, DAI, CAILI, and ZENG, HONGBO. (2018) viscoelastic surfactants with high salt tolerance, fast‐dissolving property, and ultralow interfacial tension for chemical flooding in offshore Oilfields. Journal of Surfactants and Detergents 21(4), 475-488.
  28. [28]TANG SHANFA, ZHENG, YAHUI, YANG, WEIPENG, WANG, JIAXIN, FAN, YINGKAI, and LU, JUN. (2018) Experimental study of sulfonate Gemini surfactants as thickeners for clean fracturing fluids. Energies 11(11), 3182.
  29. [29]MPELWA MUSA, TANG, SHANFA, JIN, LIJUN, and HU, RUIZHI. (2019) New sulfonate Gemini surfactants: synthesis and evaluation for enhanced oil recovery applications. Journal of dispersion science and technology, 1-9.
  30. [30]YAHUI ZHENG, SHANFA, TANG, JIAXIN, WANG, MPELWA, MUSA, MINGZHENG, PU, and TIANYUAN, ZHOU. (2019) Effect of Micelle Structure on the Viscosity of Sulfonate Gemini Surfactant Solution. Arabian Journal for Science and Engineering 44(1), 259-267.
  31. [31]MPELWA MUSA, TANG, SHANFA, JIN, LIJUN, HU, RUIZHI, WANG, CHANGQUAN, and HU, YANG. (2020) The study on the properties of the newly extended Gemini surfactants and their application potentials in the petroleum industry. Journal of petroleum science and engineering 186, 106799.
  32. [32]KOELSCH P, and MOTSCHMANN, H. (2005) Varying the counterions at a charged interface. Langmuir 21(8), 3436-3442.
  33. [33]SANTOS FRANCISCO KLEBSON G, NETO, EDUARDO L BARROS, MOURA, MARIA CARLENISE PA, DANTAS, TEREZA N CASTRO, and NETO, AFONSO A DANTAS. (2009) Molecular behavior of ionic and nonionic surfactants in saline medium. Colloids and Surfaces A: Physicochemical and Engineering Aspects 333(1-3), 156-162.
  34. [34]VAKARELSKI IU, and DUSHKIN, CD. (2000) Effect of the counterions on the surface properties of surfactant solutions: kinetics of the surface tension and surface potential. Colloids and Surfaces A: Physicochemical and Engineering Aspects 163(2-3), 177-190.
  35. [35]ZHAO T. T., GONG, H. J., XU, G. Y., CAO, X. L., SONG, X. W., and WANG, H. Y., (2010) Investigation of salts tolerance of anionic surfactants in aqueous solutions. Oilfield Chemistry 27, 112-118.
  36. [36]SHANG YAZHUO, WANG, TENGFANG, HAN, XIA, PENG, CHANGJUN, and LIU, HONGLAI. (2010) Effect of ionic liquids C n mimBr on properties of gemini surfactant 12-3-12 aqueous solution. Industrial & Engineering Chemistry Research 49(18), 8852-8857.
  37. [37]DAHANAYAKE MANILAL, COHEN, ANNA, and ROSEN, MILTON. (1986) Relationship of structure to properties of surfactants. 13. Surface and thermodynamic properties of some oxyethylenated sulfates and sulfonates. The Journal of Physical Chemistry 90(11), 2413-2418.
  38. [38]QIN AN-GUO, ZHANG, XIN-MIN, FENG, RU-SEN, and Lü, XIN. (2012) Effect of Inorganic Salt on the Surface Activity of Sulfonate Gemini Surfactant Solution. Fine Chemicals 29(2), 122-125.
  39. [39]REN ZHAO, DJ, CHEN, LUO, Y., and HUANG, J., (2010) Investigation of Influence of Inorganic Salt on the Critical Micelle Concentration of Sodium Octylphenol Polyoxyethylenated Ethylsulfonate. Acta Chimica Sinica 68(17), 1771-1775.
  40. [40]KAMAL MUHAMMAD SHAHZAD. (2016) A review of gemini surfactants: potential application in enhanced oil recovery. Journal of Surfactants and Detergents 19(2), 223-236.
  41. [41]MENGER FREDRIC M, and LITTAU, CA. (1991) Gemini-surfactants: synthesis and properties. Journal of the American chemical society 113(4), 1451-1452.
  42. [42]MPELWA MUSA, ZHENG, YAHUI, TANG, SHANFA, PU, MINGZHENG, and JIN, LIJUN. (2019) Performance optimization for the viscoelastic surfactant using nanoparticles for fracturing fluids. Chemical Engineering Communications, 1-9.
  43. [43]LI KE-XING, JING, XUE-QI, HE, SONG, REN, HAO, and WEI, BING. (2016) Laboratory study displacement efficiency of viscoelastic surfactant solution in enhanced oil recovery. Energy & fuels 30(6), 4467-4474.
  44. [44]AZAD MADHAR SAHIB, SULTAN, ABDULLAH S, NUAIM, SAMI A, MAHMOUD, MOHAMMED, and HUSSEIN, IBNEL WALEED. (2014) Could VES be a part of Hybrid option to recover Heavy oil in Complex Heavy oil Reservoirs. SPE Heavy Oil Conference-Canada, Calgary, Alberta, Canada.
  45. [45]AZAD MS, and SULTAN, AS. (2014) Extending the applicability of chemical EOR in high salinity, high temperature & fractured carbonate reservoir through viscoelastic surfactants. SPE Saudi Arabia section technical symposium and exhibition, Al-Khobar, Saudi Arabia.
  46. [46]ZHAO JIANHUI, DAI, CAILI, DING, QINFANG, DU, MINGYONG, FENG, HAISHUN, WEI, ZIYANG, CHEN, ANG, and ZHAO, MINGWEI. (2015) The structure effect on the surface and interfacial properties of zwitterionic sulfobetaine surfactants for enhanced oil recovery. RSC Advances 5(18), 13993-14001.
  47. [47]LI JIE, ZHU, RUIHUA, LIU, YU, YIN, LU, and WU, WENXIANG. (2016) Synthesis and performance of novel sulfonate Gemini surfactant with trialkyl chains. Journal of dispersion science and technology 37(3), 374-379.
  48. [48]RUAN KE, ZHANG, LING, TANG, JIAONING, and XIAO, JINXIN. (2006) Interfacial tension of the aqueous two-phase systems of cationic-anionic surfactant mixtures. Acta Physico-chimica Sinica - ACTA PHYS-CHIM SIN 22(12), 1451-1455.
  49. [49]XIAO HONG-YAN, ZHEN, ZHEN, SUN, HUAN-QUAN, CAO, XU-LONG, LI, ZHEN-QUAN, SONG, XIN-WANG, CUI, XIAO-HONG, and LIU, XIN-HOU. (2010) Molecular Dynamics Simulation of Anionic Surfactant at the Water/n-Alkane Interface. Acta Physico-Chimica Sinica 26(2), 422-428.
  50. [50]WANG DEMIN, XIA, HUIFEN, LIU, ZHONGCHUN, and YANG, QINGYAN. (2001) Study of the mechanism of polymer solution with visco-elastic behavior increasing microscopic oil displacement efficiency and the forming of steady" Oil thread" flow channels. SPE Asia Pacific oil and gas conference and exhibition, Jakarta, Indonesia.
  51. [51]LI XIN PING, YU, LI, JI, YONG QIANG, WU, BO, LI, GAN ZUO, and ZHENG, LI QIANG. (2009) New type flooding systems in enhanced oil recovery. Chinese Chemical Letters 20(10), 1251-1254.


    



 

1.6
2022CiteScore
 
 
60th percentile
Powered by  Scopus

SCImago Journal & Country Rank

Enter your name and email below to receive latest published articles in Journal of Applied Science and Engineering.