{"id":6647,"date":"2026-08-16T22:28:07","date_gmt":"2026-08-16T14:28:07","guid":{"rendered":"\/jase\/?post_type=tkuisotope&p=6647"},"modified":"2026-08-23T16:40:27","modified_gmt":"2026-08-23T08:40:27","slug":"multi-objective-optimization-of-mixed-membrane-reactors-for-autothermal-reforming-of-methane","status":"publish","type":"tkuisotope","link":"\/jase\/?tkuisotope=multi-objective-optimization-of-mixed-membrane-reactors-for-autothermal-reforming-of-methane","title":{"rendered":"Multi-objective Optimization of Mixed Membrane Reactors for Autothermal Reforming of Methane"},"content":{"rendered":"\n
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<\/i> 2018<\/a><\/p>\n<\/div>\n\n\n\n

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<\/i> Volume 21, Issue 3<\/a><\/p>\n<\/div>\n\n\n\n

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Hsuan Chang<\/i><\/a>, Yih-Hung Chen, Yun-Tsz Chen, Chii-Dong Ho<\/p>\n\n\n\n

Department of Chemical and Materials Engineering, Tamkang University, Tamsui, Taiwan 251, R.O.C.<\/p>\n<\/div>\n\n\n\n

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Received:\u00a0December 18, 2017
Accepted:\u00a0March 9, 2018
Publication Date:\u00a0August 16, 2018<\/p>\n<\/div>\n<\/div>\n\n\n\n

\"\u4e0a\u50b3\u5716\u7247\"\n\n\n

Schematic illustrations of (a) membrane reactor (MR) and (b) mixed membrane reactor (MMR) for autothermal reforming (ATR) of methane.<\/p>\n<\/div>\n<\/div>\n\n\n\n

<\/i> Copyright <\/strong>The Author(s). This is an open access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0)<\/a>, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are cited.<\/p>\n\n\n\n

Download Citation:  BibTeX <\/a>| http:\/\/dx.doi.org\/10.6180\/jase.201809_21(3).0020<\/a>  <\/p>\n\n\n\n

Download PDF<\/a><\/p>\n\n\n\n

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Autothermal reforming (ATR) of methane, which supplies the heat for endothermic steam reforming by internal combustion of methane, is an important process for synthetic gas production. The axial-distributed feeding of oxygen via a packed bed inert membrane reactor (MR) can reduce the peak temperature and improve the reactor performance. A modified MR, called mixed membrane reactor (MMR), combines permeable membrane tube wall and non-permeable tube wall provides extra degrees of freedom for reactor design and operation. For MR and MMR, this study presents the ternary-objective optimization analysis for maximizing hydrogen production rate, non-combustion selectivity and conversion of methane, using a 1D pseudo-homogeneous reactor model and the NSGA-II algorithm. Compared to MR, MMR can be operated under significantly higher oxygen permeation flux without violating the maximum temperature constraint. The non-combustion selectivity and conversion of methane of MR and MMR are close, however, the hydrogen production rate of MMR can be as high as 200% of MR.<\/p>\n\n\n\n

Keywords: Methane Reforming; Membrane Reactor; Mixed Membrane Reactor; Multi-objective Optimization<\/em><\/p>\n\n\n\n

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  1. [1] Ulber, D., “A Guide to Methane Reforming,” Chemical Engineering, January, pp. 40-46 (2015).<\/li>\n
  2. [2] Rice, S. F. and Mann, D. P., Autothermal Reforming of Natural Gas to Synthesis Gas, SAND2007-2331, Sandia National Laboratories, U.S. Department of Commerce (2007).<\/li>\n
  3. [3] Marcano, J. G. S. and Tsotsis, T. T., Catalytic Membranes and Membrane Reactors, Wiley-VCH Verlag GmbH, Weinheim Germany (2002).<\/li>\n
  4. [4] Coronas, J. and Santamaria, J., “Catalytic Reactors Based on Porous Ceramic Membranes,” Catalysis Today, Vol. 51, pp. 377-389 (1999). doi: 10.1016\/S0920-5861(99)00090-5<\/li>\n
  5. [5] Rodr\u00edguez, M. L., Ardissone, D. E., Opez, E. L., Pedernera, M. N. and Borio, D. O., “Reactor Designs for Ethylene Production via Ethane Oxidative Dehydrogenation: Comparison of Performance,” Industrial and Engineering Chemistry Research, Vol. 50, pp. 2690-2697 (2011). doi: 10.1021\/ie100738q<\/li>\n
  6. [6] Rodriguez, M. L., Pedernera, M. N. and Borio, D. O., “Two Dimensional Modeling of a Membrane Reactor for ATR of Methane,” Catalysis Today, Vol. 193, pp. 137-144 (2012). doi: 10.1016\/j.cattod.2012.04.010<\/li>\n
  7. [7] Coronas, J., Men\u00e9ndez, M. and Santamar\u00eda, J., “Use of a Ceramic Membrane Reactor for the Oxidative Dehydrogenation of Ethane to Ethylene and Higher Hydrocarbons,” Industrial and Engineering Chemistry Research, Vol. 34, pp. 4229-4234 (1995). doi: 10.1021\/ie00039a011<\/li>\n
  8. [8] \u00c1vila-Neto, C. N., Dantas, S. C., Silva, F. A., Franco, T. V., Romanielo, L. L., Hori, C. E. and Assis, A. J., “Hydrogen Production from Methane Reforming: Thermodynamic Assessment and Autothermal Reactor Design,” Journal of Natural Gas Science and Engineering, Vol. 1, pp. 205-215 (2009). doi: 10.1016\/j.jngse.2009.12.003<\/li>\n
  9. [9] Sinaei Nobandegani, M., Sardashti Birjandi, M. R., Darbandi, T., Khalilipour, M. M., Shahraki, F. and Mohebbi-Kalhori, D., “An Industrial Steam Methane Reformer Optimization Using Response Surface Methodology,” Journal of Natural Gas Science and Engineering, Vol. 36, pp. 540-549 (2016). doi: 10.1016\/j.jngse.2016.10.031<\/li>\n
  10. [10] Shahhosseini, H. R., Farsi, M. and Eini, S., “Multi-objective Optimization of Industrial Membrane SMR to Produce Syngas for Fischer-Tropsch Production Using NSGA-II and Decision Makings,” Journal of Natural Gas Science and Engineering, Vol. 32, pp. 222-238 (2016). doi: 10.1016\/j.jngse.2016.04.005<\/li>\n
  11. [11] Deb, K., Patap, A., Agarwal, S. and Meyarivan, T., “A Fast and Elitist Multiobjective Genetic Algorithm: NSGA-II,” IEEE Transactions on Evolutionary Computation, Vol. 6, pp. 182-197 (2002). doi: 10.1109\/4235.996017<\/li>\n
  12. [12] De Groote, A. M. and Froment, G. F., “Simulation of the Catalytic Partial Oxidation of Methane to Synthesis Gas,” Applied Catalysis A: General, Vol. 138, pp. 245-264 (1996). doi: 10.1016\/0926-860X(95)00299-5<\/li>\n
  13. [13] Ergun, S., “Fluid Flow through Packed Columns,” Chem. Eng. Prog., Vol. 48, pp. 89-94 (1952).<\/li>\n
  14. [14] Xu, J. and Froment, G. F., “Methane Steam Reforming, Methanation and Water-gas Shift: I. Intrinsic Kinetics,” AIChE Journal, Vol. 35, pp. 88-96 (1989). doi: 10.1002\/aic.690350109<\/li>\n
  15. [15] Mallada, R., Pedernera, M., Men\u00e9ndez, M. and Santamaria, J., “Synthesis of Maleic Anhydride in an Inert Membrane Reactor. Effect of Reactor Configuration,” Industrial and Engineering Chemistry Research, Vol. 39, pp. 620-625 (2000). doi: 10.1021\/ie9905310<\/li>\n
  16. [16] Pedernera, M., Mallada, R., Men\u00e9ndez, M. and Santamaria, J., “Simulation of an Inert Membrane Reactor for the Synthesis of Maleic Anhydride,” AICHE Journal, Vol. 46, pp. 2489-2498 (2000). doi: 10.1002\/aic.690461215<\/li>\n
  17. [17] Rodriguez, M. L., Ardissone, D. E., Lemonidou, A. A., Heracleous, E., L\u00f3pez, E., Pedernera, M. N. and Borio, D. O., “Simulation of a Membrane Reactor for the Catalytic Oxidehydrogenation of Ethane,” Industrial and Engineering Chemistry Research, Vol. 48, pp. 1090-1095 (2009). doi: 10.1021\/ie800564v<\/li>\n
  18. [18] Froment, G. F. and Bischoff, K. B., Chemical Reactor Analysis and Design, Wiley, New York, USA (1990).<\/li>\n<\/ol>\n<\/div>\n\n\n\n

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